Alat yang digunakan :
Potentiometer = 751 GPD Titrino / Titroprocessor
Electrode = 6.0133.100 pH glass electrode; input 1
6.0726.100 Ag/AgCl double junction reference electrode
(LiCl sat. in ethanol)
Pereaksi yg digunakan :
c(NaOH) = 0.1 mol/L; D0
Contoh :
app. 5-10 g minyak bunga matahari
50 mL ethanol / diethylether (1 : 1), neutralized
Rangkuman :
• Perhitungan :
Acid.No=EP1*C01/C00;2;mg/g
FFA=RS1*C02/C03;2;
Acid.No = acid number in mg KOH per g of sample
FFA = free fatty acid
C01 = mg KOH / 1 mL titrating agent (5.61)
C02 = relative molecular mass (282 for oleic acid)
C03 = factor (561)
. Jawaban
Acid.No = 0.150 x 5.61 / 10.3223 = 0.08 mg/g
FFA = 0.08 x 282 / 561 = 0.04
RS1 = 0.08
EP1 = 0.150 mL
C00 = 10.3223 g
Literature
• Metrohm Application Bulletin No. 141: Analysis of edible oils and fats.
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